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Electrosynthesis of Energy Carriers & Value-Added Products

The Halter Group @ TUM:

Electro-Organic Synthesis | Spectro-Electrochemistry | Organometallic Chemistry | Materials Science

Publications


Highlights:
Uranium-Mediated Electrocatalytic Dihydrogen Production from Water
Dominik P. Halter, Frank W. Heinemann, Julien Bachmann, Karsten Meyer,             Nature 2016, 530, 317.

The Role of Uranium–Arene Bonding in H2O Reduction Catalysis
Dominik P. Halter, Frank W. Heinemann, Laurent Maron, Karsten Meyer,               Nat. Chem. 2018, 10, 259.

Self-Adjusting Binding Pockets enhance H2 & CH4 Adsorption in a Uranium-Based Metal–Organic Framework
Dominik P. Halter, Ryan A. Klein, Michael A. Boreen, Benjamin A. Trump,
Craig M. Brown, Jeffrey R. Long,                                                                                      Chem. Sci. 2020, 11, 6709.
Electrocatalytic Transfer Hydrogenation of 1-Octene with [(tBuPCP)Ir(H)(Cl)] and Water
Patrick Mollik, Markus Drees, Alexander M. Frantz, Dominik P. Halter,                   Angew. Chem. Int. Ed. 2024, 63, e202317844.
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Pre-Prints Under Evaluation
currently none
Peer Reviewed Publications
2021 -
(20) “Endohedral Coordination of Bulky Substrates in Metalloenzyme-like Organometallic Nanotubes”
Thomas Pickl, Patrick Mollik, Markus R. Anneser, Florian Sixt, Korbinian Geißer, Oksana Storcheva, Dominik Halter, Alexander Pöthig,
Chem. Eur. J. 2025, accepted, e202500775. 

(19) “Monomeric M(II) ( M = Fe, Co, Ni) complexes supported by bulky aryloxide ligands tethered to an arene functionality; synthesis, electrochemistry and study of the M(II)-arene interaction”
Ioannis Vagiakos, Nikolaos Tsoureas, Tianyin Huang, Stella Christodoulou, Laurent Maron, Thomas Pickl, János Mink, and Dominik P. Halter,
Dalton Trans.  2025, accepted.     DOI: 10.1039/D5DT00482A 

(18) “Ex situ electro-organic synthesis: A method for unrestricted reaction control and new options for paired electrolysis”
Helena Pletsch, Yang Lyu, Dominik P. Halter,
ChemElectroChem 2024, 11, e202400489.     get ChemistryViews highlight here!

(17) “Electrocatalytic Transfer Hydrogenation of 1-Octene with [(tBuPCP)Ir(H)(Cl)] and Water ”
Patrick Mollik, Markus Drees, Alexander M. Frantz, Dominik P. Halter,
Angew. Chem. Int. Ed. 2024, 63, e202317844.

(16) “Construction and Evaluation of Cheap and Robust Miniature Ag/AgCl Reference Electrodes for Aqueous and Organic Electrolytes ”
Yang Lyu, Patrick Mollik, Attila L. Oláh, Dominik P. Halter,
ChemElectroChem 2024, 11,  e202300792.

(15) “Benzene-1,4-di(dithiocarboxylate) Linker-based Coordination Polymers of Mn2+, Zn2+ and Mixed-Valence Fe2+/3+ ”
Margit Aust, Marina I. Schönherr, Dominik P. Halter, Lena Schröck, Thomas Pickl, Simon N. Deger, Mian Z. Hussain, Andreas Jentys,
Raphael Bühler, Zihan Zhang, Karsten Meyer, Matthias Kuhl, Johanna Eichhorn, Dana D. Medina, Alexander Pöthig, Roland A. Fischer

Inorg. Chem. 2024, 63, 129.

(14) “Beyond Metal-Arenes: Monocarbonyl Ruthenium(II) Catalysts for Transfer Hydrogenation Reactions in Cancer Cells ”
Denise Lovison, Tobias Berghausen, Sophie Thomas, Jonathan Robson, Markus Drees, Christian Jandl, Patrick Mollik,
Dominik P. Halter, Walter Baratta, Angela Casini,
ACS Catal. 2023, 13, 10798.

​(13) “Non-Aqueous Electrochemistry of Uranium Complexes – A Guide to Structure-Reactivity Tuning ”
Judith Riedhammer, Dominik P. Halter, and Karsten Meyer,
Chem. Rev. 2023, 123, 7761.
2014 - 2020
(12) “Self-Adjusting Binding Pockets Enhance H2 & CH4 Adsorption in a Uranium-Based Metal–Organic Framework ”
Dominik P. Halter, Ryan A. Klein, Michael A. Boreen, Benjamin A. Trump, Craig M. Brown, and Jeffrey R. Long,
Chem. Sci. 2020, 11, 6709.

(11) ”Werner Type Complexes of Uranium(III) and (IV) ”
Judith Riedhammer, Josue R. Aguilar-Calderón, Matthias Miehlich, Dominik P. Halter, Dominik Munz, Frank W. Heinemann,
Skye Fortier, Karsten Meyer, and Daniel J. Mindiola,
Inorg. Chem. 2020, 59, 2443.

(10) “The Role of Uranium–Arene Bonding in H2O Reduction Catalysis ”
Dominik P. Halter, Frank W. Heinemann, Laurent Maron, and Karsten Meyer,
Nat. Chem. 2018, 10, 259.

(9) “Electrocatalytic H2O Reduction with f-Elements: Mechanistic Insight and Overpotential Tuning in a Series of Lanthanide Complexes ”
Dominik P. Halter, Chad T. Palumbo, Joseph W. Ziller, Milan Gembicky, Arnold L. Rheingold, William J. Evans, and Karsten Meyer,
J. Am. Chem. Soc. 2018, 140, 2587.

(8) “Using Diamagnetic Yttrium and Lanthanum Complexes to Explore Ligand Reduction and C–H Bond Activation in
a Tris(aryloxide)mesitylene Ligand System
”
Chad T. Palumbo, Dominik P. Halter, Vamsee K. Voora, Guo P. Chen, Joseph W. Ziller, Milan Gembicky, Arnold L. Rheingold, Filipp Furche,
Karsten Meyer, and William J. Evans,
Inorg. Chem. 2018, 57, 12876.

(7) “Metal Versus Ligand Reduction in Ln(III) Complexes of a Mesitylene-Anchored Tris(Aryloxide) Ligand ”
Chad T. Palumbo, Dominik P. Halter, Guo P. Chen, Alan K. Chan, Vamsee K. Voora, Megan E. Fieser, Joseph W. Ziller, Wolfgang Hieringer,
Filipp Furche, Karsten Meyer, and William J. Evans,
Inorg. Chem. 2018, 57, 2823.

(6) “1,2-CH Bond Activation of Pyridine Across a Transient Titanium Alkylidene Radical and Reformation of the Ti=CHtBu Moiety ”
Takashi Kurogi, Matthias E. Miehlich, Dominik P. Halter, and Daniel J. Mindiola,
Organometallics 2018, 37, 165.

(5) “Comparisons of Lanthanide/Actinide +2 Ions in a Tris(aryloxide)arene Coordination Environment ”
Megan E. Fieser, Chad T. Palumbo, Henry S. La Pierre, Dominik P. Halter, Vamsee K. Voora, Joseph W. Ziller, Filipp Furche,
Karsten Meyer, and William J. Evans,
Chem. Sci. 2017, 8, 7424.

(4) “Uranium-Mediated Electrocatalytic Dihydrogen Production from Water ”
Dominik P. Halter, Frank W. Heinemann, Julien Bachmann, and Karsten Meyer,
Nature 2016, 530, 317.

(3) “A Stable Crystalline Triarylphosphine Oxide Radical Anion ”
Tobias A. Schaub, Eva M. Zolnhofer, Dominik P. Halter, Tatyana E. Shubina, Frank Hampel, Karsten Meyer, and Milan Kivala,
Angew. Chem. Int. Ed. 2016, 55, 13597.

(2) ”Uranium (IV) Halide (F–, Cl–, Br–, and I–) Monoarene Complexes ”
Dominik P. Halter, Henry S. La Pierre, Frank W. Heinemann, and Karsten Meyer,
Inorg. Chem. 2014, 53, 8418.

(1) ”Coordination and Redox Isomerization in the Reduction of a Uranium(III) Monoarene Complex ”
Henry S. La Pierre, Hajime Kameo, Dominik P. Halter, Frank W. Heinemann, and Karsten Meyer,
Angew. Chem. Int. Ed. 2014, 53, 7154.
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